Nickel‐Catalyzed C( sp 2 )−C( sp 3 ) Kumada Cross‐Coupling of Aryl Tosylates with Alkyl Grignard Reagents
نویسندگان
چکیده
منابع مشابه
Activation of C ( sp 3 ) – X , C ( sp 2 ) – X , and C ( sp ) –
We systematically investigate the activation of a series of variously hybridized bonds in simple model organic compounds by palladium. These comprise the C(sp3)–X, C(sp2)–X, and C(sp)–X bonds in X–substituted ethane, ethylene, and acetylene, respectively, with X = H, CH3, and Cl. Although the bonds become stronger from sp3 to sp hybridization, the activation barriers become lower. Our analysis ...
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ژورنال
عنوان ژورنال: Advanced Synthesis & Catalysis
سال: 2019
ISSN: 1615-4150,1615-4169
DOI: 10.1002/adsc.201801586